Scientific demonstration before turning waste into treasure - tailings comprehensive utilization test
In the development and utilization of mineral resources, tailings produced by beneficiation plants are often considered "waste." Not only do they occupy significant land for tailings ponds, they can also pose environmental pollution and safety risks. However, with the increasing depletion of mineral resources, increasingly stringent environmental regulations, and technological advancements, the concept of transforming tailings into "treasure" is gaining widespread acceptance and becoming an inevitable choice for sustainable development in the mining industry. The tailings comprehensive utilization pilot is a key starting point for achieving this ambitious goal. It is not a simple technical experiment, but a complex project that integrates theoretical depth, scientific rigor, and practical guidance, aiming to provide solid scientific evidence for the high-value and diversified utilization of tailings.
01 Tailings' "Reinvention": From Waste to Potential Resource
1. Tailings Properties and Challenges
Tailings refer to solid waste discharged after ore processing through processes such as crushing, grinding, and beneficiation. It contains no or minimal useful minerals, or the useful mineral content is below the grade that can be recovered under current economic and technical conditions. Its main components include:
Gange minerals: quartz, feldspar, calcite, dolomite, mica, etc.
Minor unrecovered useful minerals: Fine particles or associated useful minerals that cannot be fully recovered due to embedded particle size and beneficiation process limitations.
Harmful elements: Sulfides (such as pyrite and arsenopyrite) and heavy metals, which may cause acidic wastewater and heavy metal leaching.
Residual beneficiation reagents: Trace amounts of flotation reagents and flocculants.
These characteristics mean that tailings not only occupy a large amount of land but also pose environmental risks. According to statistics, the global tailings production volume reaches tens of billions of tons each year, and the storage pressure is enormous.
2. Tailings Resource Utilization Potential
However, tailings are not entirely useless. Under a microscope, tailings particles are still aggregates of minerals with specific physical and chemical properties. At a macroscopic level, their vast volume holds enormous potential value:
Useful Associated Minerals: Many tailings still contain low-grade valuable metals (copper, iron, gold, silver, rare earth elements, lithium, etc.) or non-metallic minerals (fluorite, apatite, potassium feldspar, etc.), but current processes hinder their efficient recovery.
Building Materials: The silicon, aluminum, and calcium in tailings make them high-quality raw materials for building materials such as cement, bricks and tiles, ceramics, concrete aggregates, and aerated concrete.
Environmental Remediation Materials: Some tailings have adsorption properties and can be used for heavy metal wastewater treatment; desulfurized tailings can be used for soil improvement.
Agricultural Uses: Tailings that have been decontaminated and adjusted in composition can be used as soil conditioners or fertilizer carriers.
New Materials: Ultrafine tailings powder can be used to prepare microcrystalline glass, refractory materials, and composite materials.
The "identity reshaping" of tailings is based on a new understanding of their intrinsic value, and the comprehensive utilization experiment of tailings is the scientific cornerstone for achieving this reshaping.
02 The Scientific Connotation and Phases of Tailings Comprehensive Utilization Pilots
The tailings comprehensive utilization pilot is a systematic project that integrates multiple disciplines and technologies. Its core goal is to identify the most economically viable, technically feasible, and environmentally friendly utilization pathway for tailings.
1. Pre-pilot Basic Research: A Comprehensive "Physical Examination"
The successful utilization of any tailings relies on a deep understanding of its physical and chemical properties. This phase is like a comprehensive "physical examination" of the tailings.
★ Tailings Composition Analysis:
Chemical Multi-element Analysis: Accurately measures the content of major, minor, and trace elements, particularly potentially useful elements (such as rare metals, precious metals, and associated iron) and harmful elements (such as sulfur, aspergillus, cadmium, and lead). This determines the tailings' value for secondary beneficiation and the environmental risks of subsequent utilization.
Phase Analysis: X-ray diffraction (XRD) determines the mineralogical composition and quantitatively analyzes the content of each mineral, which is the foundation for understanding the physical and chemical properties of tailings.
Spectroscopic Analysis (EDS, XRF): Assists in determining the elemental distribution.
★ Physical Property Measurement:
Particle Size Composition Analysis: Screening methods, laser particle size analyzers, and other methods are used to determine tailings particle size distribution, providing a basis for processes such as grinding, grading, filling, and sintering. For example, fine tailings may require more refined grinding in the construction material industry, while affecting slurry rheology during filling.
Density Measurement: True density and bulk density, among other parameters, influence transportation, storage, and mix ratio calculations.
Specific Surface Area Measurement: BET method, which influences adsorption, reactivity, and sintering performance.
Moisture Content and Porosity: These methods influence dehydration and compaction performance.
★ Structural and Morphological Analysis:
Scanning Electron Microscopy (SEM) combined with Energy Dispersive Spectroscopy (EDS): Observes the morphology, structure, surface characteristics, and elemental distribution of tailings particles.
2. Experimental Research Phase: Exploring and Optimizing Multiple Pathways
Based on the results of basic research, combined with market demand and current technological capabilities, targeted utilization trials will be conducted.
★ Secondary Resource Recovery Trials:
Regrinding and Re-selection: For tailings containing low-grade useful minerals, the economics of regrinding and the potential for recovery through fine-grain flotation, gravity separation, and magnetic separation will be evaluated. For example, regrinding and re-selection of copper tailings can recover residual copper, sulfur concentrate, and even associated gold and silver.
Leaching Technology: For tailings containing difficult-to-select, ultra-fine particles, or associated precious metals, hydrometallurgical technologies such as cyanide leaching, acid leaching, and bioleaching are considered.
Typical Case: Magnetic separation was used to recover some magnetite from a domestic iron ore tailings, increasing the grade to over 60%, achieving economic benefits.
★ Building Material Utilization Trials:
Cement Admixtures: Tailings are used to replace a portion of cement clinker or aggregate. These trials require measurements of activity index, standard consistency water consumption, and setting time.
Sintered bricks and tiles: Tailings partially replace clay. Testing requires optimization of parameters such as batching, molding, sintering temperature, sintering time, compressive strength, water absorption, and frost resistance.
Concrete aggregate: Tailings sand replaces river sand. Grading, crushing value, and harmful substance content must be measured, and concrete mix proportion, strength, and durability tests must be conducted.
Aerated concrete, glass-ceramics, ceramics, etc.: Targeted formulation design and process parameter optimization are performed.
Typical case: Tailings bricks meeting national standards were successfully produced from a non-ferrous metal mine through dehydration, drying, and mixing, enabling large-scale industrial production.
★ Filling material testing:
Cementitious filling: Tailings are used as aggregate and mixed with cementitious materials (cement, ground slag, etc.) to prepare a filling slurry for filling underground goafs. Testing requires determination of rheological properties (slump, spread), setting time, early and late strength, as well as impermeability and crack resistance.
Paste Backfill: Preparation and transport performance of high-concentration tailings slurry, as well as fill strength.
Typical Case: A gold mine adopted a fully cemented tailings backfill technology, which not only solved the tailings storage problem but also ensured mining safety.
★ Environmental Remediation and Agricultural Utilization Experiments:
Heavy Metal Adsorption: Evaluating the adsorption capacity of tailings for heavy metal ions in wastewater.
Soil Conditioner: Evaluating the improvement effect of tailings on acidic and infertile soils (pH, nutrient content, and plant growth tests).
Typical Case: Tailings from a phosphate mine, rich in calcium, phosphorus, and other elements, were treated and used as a carrier for agricultural phosphate fertilizer, achieving increased production and efficiency.
★ Other High-Value Utilizations: Such as the preparation of composite materials, functional ceramics, and molecular sieves. This type of research typically involves more cutting-edge technologies and higher added value.
3. Environmental Impact and Economic Assessment: Dual Considerations
Environmental Impact Assessment: An assessment of environmental safety during testing and after product use. For example, radioactivity, heavy metal leaching, and dust emissions from tailings construction materials are assessed. Leachate testing is also performed after filling the tailings.
Economic Assessment: A full Life Cycle Cost Analysis (LCA) is conducted, encompassing tailings pretreatment costs, utilization process costs, product sales revenue, and environmental benefit conversions, to ensure the commercial viability of the utilization plan.
03 Practical Guidance: Ensuring Trial Success and Project Implementation
1. Clarify Trial Objectives and Demand-Oriented Design
Before the trial begins, the primary objective must be clearly defined: is it to recover by-products? To produce building materials? Or for underground backfill? Different objectives dictate different test emphases and evaluation criteria. At the same time, thorough market research should be conducted to ensure the competitiveness of the developed product.
2. Standardized Sampling and Representativeness
The properties of tailings are influenced by various factors, including ore source, beneficiation process, and storage time, and exhibit a certain degree of variability. Therefore, standardized sampling is crucial to ensure representative samples that truly reflect the average properties of the tailings. Multi-point, multi-layer, and multiple sampling, along with mixed and reduced sampling, is recommended.
3. Strictly Control the Trial Process and Record Data
Standardize Trial Parameters: All tests should be conducted under controlled variables and strictly adhere to national or industry standards.
Ensure Reliable Data: Detailed records of each test condition, operating procedures, raw data, and observations should be kept to ensure data authenticity and verifiability.
Repeatability Testing: Key experiments should be repeated multiple times to verify the accuracy and stability of the results.
Pilot-Scale-Up: After successful laboratory research, continuous pilot-scale testing should be conducted to verify the industrial feasibility of process parameters, equipment selection, and product performance, and to identify potential issues.
4. Emphasize Multi-Stakeholder Collaboration and Industry Chain Synergy
Comprehensive tailings utilization often involves multiple industries, such as mining, building materials, chemicals, and agriculture, requiring the integration of multiple resources.
Technical Cooperation: Collaborate with universities and research institutes to introduce advanced technologies and professional talent.
Policy Support: Actively seek preferential government policies in terms of funding, land, and taxation.
Market Connectivity: Establish connections with potential users to jointly develop and promote tailings products.
5. Prioritize Safety and Environmental Protection
Regardless of the utilization method, safety and environmental protection must be prioritized. Ensure that tailings utilization products meet relevant national standards and do not cause secondary harm to the environment and human health. For example, tailings used in agriculture must pass rigorous testing for heavy metal leaching, toxicity, and radioactivity.
04 Outlook: The Future of Tailings Utilization
In the future, comprehensive tailings utilization will develop towards high-value-added, diversified, intelligent, and zero-emission development.
High-value development: Shifting from extensive building material utilization to high-value-added products such as rare metals, precious metals, and high-purity materials.
Diversification: Integrating multidisciplinary technologies to develop more innovative applications.
Intelligence: Introducing big data, artificial intelligence, and robotics to achieve intelligent tailings sorting, automated batching, and process optimization.
Zero-emission: The ultimate goal is to achieve 100% tailings utilization, completely eliminating tailings ponds or transforming them into eco-friendly landscapes.
Trials in comprehensive tailings utilization are essential for the mining industry to achieve green development and a circular economy. It goes beyond simply turning waste into treasure; it demonstrates a deep respect for and efficient utilization of Earth's resources. Through in-depth scientific research, rigorous experimental practice, and multi-stakeholder collaboration, we have the ability and responsibility to transform tailings, once a burden, into a valuable asset that drives industry progress and benefits human society. This requires not only technological breakthroughs, but also conceptual innovation and the joint efforts of the entire society.