What is Lead Zinc Ore Flotation Process Use Reagents Recommended?
1. What is Lead-Zinc mine?
Lead Zinc ore refers to a mineral rich in the metal elements Lead and Zinc, usually Sulfides or Oxides. The useful minerals of Lead-Zinc ore are mainly galena (PbS) and sphalerite (ZnS), in addition to white Lead ore (PbCO3), Lead alum (PbSO4), Sphalerite (ZnCO3), and Sphalerite (Zn5 (CO3) 2 (OH) 6). The types of ores are complex, with few single Lead or Zinc ore types. Most Lead-Zinc deposits are commonly associated with more than 50 elements, mainly including Gold, Silver, Copper, Tin, Cadmium, Sulfur, Fluorite, and rare dispersed elements.
Galena belongs to the equiaxed crystal system, with crystals in the form of cubes or aggregates of cubes and octahedra, usually in the form of Lead gray, metallic luster granular or block aggregates. Another important feature of galena is the development of three sets of completely perpendicular cleavage, which can easily break into small cubic pieces.
Sphalerite has an equiaxed crystal system, with crystals appearing tetrahedral and usually in granular aggregates; The color changes from light yellow to brown, and even black, as the iron content increases; The stripes range from white to brown, with a resin luster to semi metallic luster, and transparent to semi transparent.
2. Classification
Ⅰ. Sulfide type Lead-Zinc ore: mainly including Sphalerite, Galena, etc.
Ⅱ. Oxidized Lead-Zinc ores: mainly including Sphalerite, Ilmenite, etc.
3. Characteristics
Ⅰ. Sulfide type Lead-Zinc ore: usually black or dark gray in color, with metallic luster, high hardness, and high specific gravity.
Ⅱ. Oxidized Lead-Zinc ore: usually white or light yellow in color, with a glassy luster, low hardness, and low specific gravity.
4. Distribution
Distributed around the world, mainly concentrated in North America, Europe, and Asia. China is also one of the important production areas, mainly distributed in Shaanxi, Guizhou and other places.
5. Recommended Reagents for Lead Zinc ore flotation as below:
Lead collectors:
Collector HYDR420
【Characteristics】Yellow to brown liquid
【Specification】1200kg/IBC drum or 240kg/drum
【Function】Used for flotation separation of Lead-Zinc Sulfide ore, Copper Zinc Sulfide ore, and Copper Lead-Zinc Sulfide ore, it has strong collection ability for Copper and Lead, weak collection ability for Zinc, and can significantly improve the grade and yield of Copper and Lead concentrates, while greatly reducing the mutual inclusion of Zinc in Copper Lead concentrates. Weak capturing power for Pyrite and Magnetite, suitable for high Sulfur Copper and high Sulfur Copper Gold mines, can reduce the dosage of lime or sulfur depressants. Lead ore has strong capture ability and can be directly used for flotation without pre sulfurization. This product is a liquid that does not require dissolution and is easy to use. It is an excellent alternative to solid Xanthate and MBT, and can be used alone or in combination with other collectors.
Collector HYDR620
【Characteristics】Yellow oily liquid
【Specification】1100kg/IBC drum or 220kg/drum
【Typical applicable minerals】Iron ore desulfurization, Pyrite, Copper Sulfide ore, Nickel Sulfide ore, Lead-Zinc Sulfide ore, Gold ore
【Function】This product is an oil based collector that is insoluble in water and belongs to the organic chelating class. Mainly used for flotation of Sulfide ores containing Copper, Lead, Zinc, and Nickel that are difficult to select. The product has stable properties and is suitable for use within the pH range of 4-12. When the particle recovery rate is low, the product is also suitable and very effective for excessive grinding of Molybdenite and Galena. Due to its insolubility in water, this product is not easily adsorbed by gangue minerals such as clay, talc, and chlorite, which can effectively improve the grade of the concentrate. Under acidic conditions, it has strong capturing power for Pyrite and is applied in Pyrite flotation and iron ore desulfurization. Its dosage is about 50% to 80% of the dosage of Xanthate, and the flotation efficiency is much better than that of xanthate. When the pH of the slurry is greater than 8, the product has weak collection ability for Pyrite and is an excellent collector for low alkalinity sulfide flotation. At the same time, this product has strong capturing power for rare and precious metals such as Gold and Silver, and can be used as a Gold and Silver mineral collector or auxiliary collector.
Collector YX3418A-6
【Characteristics】Brown transparent liquid
【Water soluble】Slightly soluble in water
【Specification】1000kg/IBC drum or 200kg/drum
【Typical applicable minerals】Lead-Zinc sulfide ore
【Function】This product is suitable for Lead Zinc Sulfide minerals and is an excellent collector for Lead Sulfide minerals. Applied in the Lead flotation stage, it has strong capturing power for Lead Sulfide and weak capturing power for Zinc Sulfide and Pyrite. It can significantly improve the grade and recovery rate of Lead Sulfide, while reducing Zinc and Sulfur in Lead concentrate. It is an efficient collector for Lead Zinc separation.
Zinc collector:
Collector YX091
【Characteristics】Light yellow to dark yellow transparent oily liquid
【Specification】1000kg/IBC drum or 200kg/drum
【Function】Highly efficient collector for Sulfide ores, with weak foaming properties, mainly used for flotation of difficult to select Copper Sulfide, Copper Gold Sulfide ores, and Zinc Sulfide ores. It can effectively improve the recovery rate of mineral processing and is an excellent substitute for ethylenethiourea.
Collector Z1020S
【Characteristics】Light yellow to yellow liquid
【Specification】1000kg/IBC drum or 200kg/drum
【Function】Zinc Sulfide is an efficient collector with strong foaming properties, mainly used in Zinc flotation processes for Sulfide ores such as Copper Zinc, Lead Zinc, and Copper Lead Zinc, which can reduce the amount of frother used. This product has extremely strong collection ability and good selectivity for Zinc Sulfide, but weak collection ability for Pyrite and Magnetite, and can achieve Zinc Sulfur separation under low alkalinity conditions. Compared with traditional Zinc collectors such as Xanthate, the use of this product can reduce the amount of Copper Sulfate, lime, or other sulfur depressants, while ensuring the grade of Zinc concentrate and significantly improving the recovery rate of Zinc concentrate.
Frothers:
Frother Q70
【Characteristics】Yellow transparent liquid
【Water soluble】Partially soluble in water
【Specification】950kg/IBC drum or 190kg/drum
【Typical applicable minerals】Copper Sulfide ore, Copper Gold Sulfide ore, Copper Lead Zinc Sulfide ore, etc
【Function】Suitable for flotation of various nonferrous metal Sulphide ores. Under small consumption, there are many foam formed, and the bubbles have the characteristics of reasonable size distribution, moderate toughness, and low viscosity; It has good fluidity and appropriate water solubility, is non-toxic, odorless, non corrosive, and easy to transport, add, and other operations. The foaming performance is not (or minimally) affected by the pH value of the slurry or other components in the slurry (such as inevitable ions and other flotation reagents); It does not have a capturing effect and does not affect the selectivity of the capturing reagent.
Frother Q60
【Characteristics】Yellow to brownish yellow oily liquid
【Specification】950kg/IBC drum or 190kg/drum
【Function】Has a fast foaming rate and strong foaming ability, and is suitable for the beneficiation of non-ferrous metal ores and rare and precious metal ores, especially for the beneficiation of non-ferrous metal ores with a high proportion of target minerals and high content of mudstone gangue.
Frother Q80
【Characteristics】Colorless Transparent Liquid
【Water soluble】Partially soluble in water
【Specification】1000kg/IBC drum or 200kg/drum
【Typical applicable minerals】Copper Sulfide ore, Copper Gold Sulfide ore, Copper Lead Zinc Sulfide ore, etc
【Function】This frother forms stable foam by reducing the Surface tension of water. The non-polar group of the frother can form strong adsorption with the hydrophobic group of traditional collectors and third-generation ester reagents, so that the target mineral particles can be stably attached to the air bubble and selectively attached to achieve the flotation of the target mineral. Because of its small foam viscosity, normal distribution of foam diameter and low liquid carrying capacity, the foam is fresh and not easy to be directly adsorbed with hydrophilic gangue or minerals, and the entrainment effect is minimal, which can ensure the flotation recovery rate and also improve the grade of concentrate. Applied to Copper Sulfide ores, Copper Gold Sulfide ores, Copper Lead Zinc Sulfide ores, etc., it is an efficient flotation frother for non-ferrous metal Sulfide ores.