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What Is The Method For Extracting Gold From E-waste With An Eco-friendly Gold Extractant And Detecting The Cyanide Concentration?

Gold Recovery from E-Waste Using Eco-Friendly Extraction Reagents I. Pretreatment Steps 1.1 Crushing and Screening Purpose: Increase surface area to facilitate subsequent gold leaching. Operations: ① Use a crusher to break down e-waste (e.g., circuit boards, CPUs, gold fingers) into 0.5–1 mm particles. ② Screen the material to remove oversized or undersized particles, ensuring uniform particle size. ③ Employ magnetic separation to remove ferromagnetic impurities (e.g., iron, nickel). ④ Rinse the crushed material with clean water to eliminate dust and impurities, then air-dry for further use.   1.2 Roasting Treatment (Optional) Purpose: Remove organic materials and break the bonding between metals and plastics. Operations: ① Place the crushed e-waste in a roasting furnace and roast at 500–600°C for 1–2 hours. ② Ensure proper ventilation during roasting to prevent the accumulation of harmful gases. ③ After roasting, allow the waste to cool to room temperature, then perform secondary crushing until the particle size is less than 0.5 mm.   II. Preparation of Eco-Friendly Gold Extraction Agent YX500 Solution 2.1 Preparation of Eco-Friendly Gold Extraction Agent YX500 Solution Reagent: Eco-friendly gold extraction agent YX500. Concentration: Prepare a YX500 solution with a concentration of 0.05%–0.1% (i.e., 0.5–1 g/L). Method: ① Add an appropriate amount of clean water into the mixing tank. ② Slowly add the eco-friendly gold extraction agent YX500 in proportion while continuously stirring until it is completely dissolved. ③ Dosing time: Ensure the operation is completed within 10–20 minutes.   2.2 Alkalinity Adjustment Purpose: Prevent hydrogen cyanide gas volatilization and ensure smooth leaching reaction. Operations: ① Add sodium hydroxide (NaOH) or lime milk to adjust the solution pH to 10–11. ② Use pH test strips or a pH meter to verify the solution's alkalinity reaches the appropriate level.   III. Leaching Process 3.1 Leaching Equipment Equipment: Tower leaching tank or mechanically agitated tank. Temperature: Ambient temperature (20–25°C). If leaching acceleration is required, temperature may be increased to 40–50°C.   3.2 Reagent Addition & Reaction Conditions Dosing sequence: ① First, add sodium hydroxide (NaOH) solution for pH adjustment. ② Then, add the pre-prepared eco-friendly gold extraction agent YX500 solution and start the stirring device. ③ Dosing time: Must be completed within 10–20 minutes. Stirring speed: 200–300 rpm to ensure full contact between materials and solution.   3.3 Leaching Time & Oxidant Usage Leaching time: At ambient temperature: 24–48 hours. At 40–50°C: Can be reduced to 12–24 hours. Oxidant: ① To accelerate gold dissolution, hydrogen peroxide (H₂O₂, 0.1–0.5%) may be added or air may be introduced. ② Addition timing: Synchronized with the YX500 solution dosing and maintained continuously.   IV. Solid-Liquid Separation Filtration and Washing Method: Vacuum filtration or centrifugal separation equipment shall be employed. Operations: ① Filter the leached slurry to separate the gold-bearing solution (pregnant solution) from the residue. ② Wash the residue with dilute alkaline solution (pH 10-11) to recover residual gold elements.   V. Gold Recovery Methods Method 1: Zinc Powder Replacement Process Steps: ① Slowly add zinc powder to the pregnant solution at a ratio of 5-10 g/L. ② Maintain continuous stirring with a reaction time of 2-4 hours. ③ Filter to obtain gold mud.   Method 2: Electrolysis Process Equipment: Stainless steel cathode, graphite or lead anode. Conditions: ① Current density: 1-2 A/dm², Voltage: 2-3 V. ② Electrolysis duration: 6-12 hours. Operations: ① After energizing the electrolytic cell, gold gradually deposits on the cathode. ② Remove the cathode and scrape off the deposited gold mud.   VI. Gold Mud Treatment and Refinement Acid Washing and Smelting Steps: ① Use dilute nitric acid or aqua regia to dissolve impurities, followed by filtration to obtain purified gold mud. ② Place the gold mud in a high-temperature electric furnace for smelting, then cast into gold ingots. Purity: Can reach ≥99.9%.   VII. Waste Liquid Treatment and Environmental Protection Measures Compliant Discharge Testing: Verify cyanide concentration to ensure it remains below 0.2 mg/L. Discharge: After meeting standards, release into wastewater treatment system.   VIII. Safety Precautions ① Ventilation: Maintain adequate ventilation in work areas to prevent hydrogen cyanide gas accumulation. ② Protection: Operators must wear gloves, masks, and protective goggles to ensure safety. ③ First Aid: Prepare amyl nitrite and other antidotes for emergency treatment of cyanide poisoning.       Detection of Cyanide Ion (CN¯) Concentration in Eco-Friendly Gold Extraction Reagents   Testing the cyanide ion (CN¯) concentration in eco-friendly gold extraction agents is a critical step to ensure their safety and effectiveness. The following outlines commonly used detection methods and their key operational points, categorized into two main types: laboratory testing methods and on-site rapid testing methods.   I. Laboratory Precision Detection Methods 1.1 Silver Nitrate Titration (Classical Method) Principle: Cyanide ions react with silver nitrate to form soluble [Ag(CN)₂]¯ complexes, with excess silver ions reacting with an indicator (e.g., silver chromate) to produce a color change. Steps: ① Dilute the sample and add sodium hydroxide (pH >11) to prevent hydrogen cyanide (HCN) volatilization. ② Use silver chromate as an indicator and titrate with standardized silver nitrate solution until the color changes from yellow to orange-red. Scope: Suitable for high cyanide concentrations (>1 mg/L); provides precise results but requires laboratory conditions.   1.2 Spectrophotometry (Isonicotinic Acid-Pyrazolone Method) Principle: In weakly acidic conditions, cyanide reacts with chloramine-T to form cyanogen chloride (CNCl), which then reacts with isonicotinic acid-pyrazolone to produce a colored compound. Quantification is achieved by measuring absorbance at 638 nm. Steps: ① Distill the sample if necessary to remove interferents. ② Add buffer and chromogenic reagents, then measure absorbance using a spectrophotometer. Calculate concentration via a standard curve. Advantage: High sensitivity (detection limit: 0.001 mg/L), ideal for trace-level analysis.   1.3 Ion-Selective Electrode (ISE) Method Principle: A cyanide electrode responds to CN¯ activity, measuring concentration via potential difference. Steps: ① Adjust sample pH to >12 with NaOH to avoid HCN interference. ② Calibrate the electrode, measure potential, and convert to concentration. Advantage: Rapid operation, broad detection range (0.1–1000 mg/L), but requires regular electrode calibration.   II. On-Site Rapid Detection Methods 2.1 Rapid Test Strips Principle: Strips contain chromogenic agents (e.g., picric acid) that change color (yellow to reddish-brown) upon reaction with cyanide ions. Procedure: Immerse the strip in the sample, then compare the color against a reference card for semi-quantitative reading. Features: Highly portable but relatively low accuracy; suitable for emergency screening.   2.2 Portable Cyanide Detectors Principle: Miniaturized spectrophotometric or electrode-based devices (e.g., Hach, Merck). Operation: Direct sample injection with automatic concentration display. Advantage: Combines speed and high precision, ideal for field use in mining areas.   2.3 Pyridine-Barbituric Acid Colorimetry (Simplified) Reagent Kit: Pre-packaged tubes with chromogenic agents; add water sample for colorimetric analysis. Detection Limit: ~0.02 mg/L, suitable for low-cyanide testing in eco-friendly gold extraction agents.   III. Precautions Safety Measures Cyanide is highly toxic! All testing must be conducted in a fume hood to prevent skin contact or inhalation. Waste liquid treatment: Oxidize with sodium hypochlorite (CN¯ + ClO¯ → CNO¯ + Cl¯). Interference Factors Sulfide (S²¯) and heavy metal ions may cause interference. Pre-distillation or masking agents (e.g., EDTA) should be used to eliminate their effects. Method Selection High-precision testing: Laboratory titration or spectrophotometry is preferred. Rapid screening: Test strips or portable devices are more practical.  

What Is The Beneficiation Process For Lead-Zinc Ore?

  Chapter 1: Characteristics of Lead-Zinc Ore Resources and Beneficiation   1.1 Global Resource Distribution Features Main Mineralization Types: Sedimentary Exhalative Deposits (55%) Mississippi Valley-Type Deposits (30%) Volcanogenic Massive Sulfide (VMS) Deposits (15%) Representative Deposits: China's Fankou Deposit (Proven reserves: Pb+Zn >5 million tonnes) Australia's Mount Isa Mine (Average zinc grade: 7.2%) Mineralogical Associations: Intimate PbS-ZnS intergrowth (Particle size distribution: 0.005-2mm) Precious metal associations (Ag content: 50-200g/t, often occurring as argentiferous galena)   1.2 Process Mineralogy Challenges Variable Iron Content in Sphalerite (Fe 2-15%): Impacts flotation behavior due to changes in surface chemistry, High-iron sphalerite (>8% Fe) requires stronger activation Secondary Copper Minerals (e.g., Covellite): Causes copper contamination in zinc concentrates (typically >0.8% Cu), Requires selective depression reagents (e.g., Zn(CN)₄²⁻ complexes) Slime Coating Effects: Becomes significant when -10μm particles exceed 15%, Mitigation methods: ---Dispersion agents (sodium silicate) ---Stage grinding-flotation circuits       Chapter 2: Modern Beneficiation Process Systems 2.1 Standard Selective Flotation Process Grinding and Classification Control ---Primary Closed-Circuit Grinding: Hydrocyclone classification, Circulating load: 120-150% ---Target Fineness: 65-75% passing 74μm, Galena liberation degree: >90% Lead Flotation Circuit ---Reagent Scheme: Reagent Type Dosage (g/t) Mechanism of Action Lime 2000-4000 pH adjustment to 9.5-10.5 Diethyl dithiocarbamate (DTC) 30-50 Selective galena collector MIBC (frother) 15-20 Froth stability control ---Equipment Configuration: JJF-8 Flotation Cells: 4 cells for roughing + 3 cells for cleaning Zinc Activation Control ---CuSO₄ Dosage: 250±50 g/t, Optimized with mixing intensity (power density: 2.5 kW/m³) ---Potential (Eh) Control Range: +150 to +250 mV   2.2 Innovative Bulk Flotation Technology Key Technological Breakthroughs: ---High-efficiency composite collector (AP845 + ammonium dibutyl dithiophosphate, 1:3 ratio) ---Selective depression removal technology (pH adjustment to 7.5±0.5 using Na₂CO₃) Industrial Application Cases: ---Throughput increased by 22% (reaching 4,500 t/d) at an Inner Mongolia mine ---Zinc concentrate grade improved by 3.2 percentage points   2.3 Dense Media Separation-Flotation Combined Process Pre-concentration Subsystem: ---Medium density control (magnetite powder D50=45μm) ---Three-product cyclone (DSM-800 type) separation efficiency Ep=0.03 Economic Analysis: ---When waste rejection rate reaches 35-40%, grinding costs are reduced by 28-32%       Chapter 3: Lead-Zinc Ore Beneficiation Reagents 3.1 Collector Types & Applications (1) Anionic Collectors Reagent Target Mineral Dosage (g/t) pH Range Notable Features Xanthates (e.g., SIPX) ZnS 50-150 7-11 Cost-effective, requires CuSO₄ activation Dithiophosphates (DTP) PbS 20-60 9-11 High Pb selectivity over Zn Fatty acids Oxidized ores 300-800 8-10 Needs dispersants (e.g., Na₂SiO₃) (2) Cationic Collectors Amines (e.g., Dodecylamine): Used in reverse flotation for silicate removal, Dosage: 100-300 g/t, pH 6-8 (3) Amphoteric Collectors Amino-carboxylic acids: Selective for Zn in complex ores, Effective at pH 4-6 (Eh = +200 mV)   3.2 Depressants & Modifiers Reagent Function Dosage (kg/t) Target Impurities Na₂S Zn depression in Pb circuit 0.5-2.0 FeS₂, ZnS ZnSO₄ + CN⁻ Pyrite depression 0.3-1.5 FeS₂ Starch Silicate depression 0.2-0.8 SiO₂ Na₂CO₃ pH modifier (buffer at 9-10) 1.0-3.0 -   3.3 Composite Reagents for Lead-Zinc Ore Beneficiation Composite beneficiation reagents refer to multifunctional reagent systems formed by integrating two or more functional components (collectors, depressants, frothers, etc.) through physical blending or chemical synthesis. Based on their composition, they can be classified into: (1) Physically Blended Type Mechanical mixing of individual reagents (e.g., diethyldithiocarbamate (DTC) + butyl xanthate at a 1:2 ratio) Typical example: LP-01 composite collector (xanthate + thiocarbamate) (2) Chemically Modified Type Molecularly engineered multifunctional reagents Typical examples: Hydroxamic acid-thiol complexes (dual collector-depressant functionality) Zwitterionic polymer depressants       Chapter 4: Key Equipment and Technical Parameters 4.1 Flotation Equipment Selection Guide Roughing Stage: KYF-50 flotation machine (aeration rate: 1.8 m³/m²·min) Cleaning Stage: Flotation column (Jameson Cell, bubble diameter: 0.8-1.2 mm) Comparative Test Data: Conventional mechanical vs. aerated cells: Recovery rate difference of ±3.5% 4.2 Process Control Systems Online Analyzer Configuration: ---Courier SLX (slurry XRF, analysis cycle: 90 s) ---Outotec PSI300 (particle size analysis, error 85%) Reuse Water Standards: ---Heavy metal ion concentrations (Pb²⁺65%) ---Sulfur concentrate production (combined magnetic separation-flotation, S grade >48%) Bulk Utilization Methods: ---Cement additive (15-20% blending ratio) ---Underground backfill material (slump control 18-22 cm)       Chapter 6: Techno-Economic Indicator Comparison 6.1 Typical Concentrator Operating Data Production Cost Structure: Cost Item Proportion (%) Unit Cost (USD/t)* Grinding Media 28-32 1.2-1.5 Flotation Reagents 18-22 0.75-1.05 Energy Consumption 25-28 1.05-1.35 *Note: Currency conversion at 1 CNY ≈ 0.15 USD 6.2 Technological Upgrade Benefits Case Study: 2,000 t/d Concentrator Retrofit Parameter Before Retrofit After Retrofit Improvement Zinc Recovery 82.3% 89.7% +7.4% Reagent Cost 6.8 CNY/t 5.2 CNY/t -23.5% Water Reuse Rate 65% 92% +27%       Chapter 7: Future Technological Development Directions 7.1 Short-Process Separation Technologies Superconducting Magnetic Separation (Background field intensity: 5 Tesla, processing -0.5mm material) Fluidized Bed Separation (Air-dense medium fluidized bed, Ecart Probable Ep=0.05) 7.2 Green Beneficiation Breakthroughs Bio-Reagent Development (e.g., Lipopeptide-based collectors) Zero-Tailings Mine Construction (Comprehensive utilization rate >95%)

What Are The Methods For Phosphate Ore Beneficiation?

1 Overview of Phosphate Ore Phosphate ores in nature are mainly classified into apatite-type (e.g., fluorapatite Ca₅(PO₄)₃F) and sedimentary phosphorite (e.g., collophanite). Due to significant variations in raw ore grades (P₂O₅ content ranging from 5% to 40%), beneficiation processes are typically required to enhance the grade to meet industrial standards (P₂O₅ ≥ 30%). Phosphate ores are rich in phosphorus, primarily used for extracting phosphorus and producing related chemical products, such as widely known phosphate fertilizers, as well as common industrial chemicals like yellow phosphorus and red phosphorus. These phosphorus-based materials, derived from phosphate ores, find extensive applications in agriculture, food, medicine, chemicals, textiles, glass, ceramics, and other industries. Given the generally high floatability of phosphate ores, flotation is the most commonly employed beneficiation method.       2 Phosphate Ore Beneficiation Methods   The selection of phosphate ore beneficiation processes depends on ore type, mineral composition, and dissemination characteristics. The primary methods include: Scrubbing and desliming, Gravity separation, Flotation, Magnetic separation, Chemical beneficiation, Photoelectric sorting, and Combined processes. 2.1 Scrubbing and Desliming Process This method is particularly suitable for heavily weathered phosphate ores with high clay content (such as certain sedimentary phosphorites). The technological process consists of: Crushing and Screening: Raw ore is crushed to appropriate particle size (e.g., below 20mm) Scrubbing: Employing scrubbers (like trough scrubbers) with water agitation to separate clay and fine slimes Desliming: Using hydrocyclones or spiral classifiers to remove slime particles smaller than 0.074mm Advantages: Features simple operation and low cost, capable of increasing P₂O₅ grade by 2-5% Limitations: Shows limited effectiveness for processing ores with closely intergrown minerals 2.2 Gravity Separation This method is applicable to ores where phosphate minerals and gangue exhibit significant density differences (e.g., apatite-quartz associations). Commonly used equipment includes: Jigging Machines: Ideal for processing coarse-grained ore (+0.5mm) Spiral Concentrators: Effective for medium-fine particle separation (0.1-0.5mm) Shaking Tables: Specialized for precision separation Advantages: Chemical-free process, making it particularly suitable for water-scarce regions Limitations: Relatively lower recovery rates (approximately 60-70%); Ineffective for processing ultra-fine particle ores 2.3 Flotation Method The most widely applied beneficiation technology for phosphate ores, particularly effective for processing: Low-grade collophanite ores, Complex disseminated ore types 2.3.1 Direct Flotation (Phosphate Mineral Flotation) Reagent Scheme: Collector: Fatty acids (e.g., oleic acid, oxidized paraffin soap) Depressant: Sodium silicate (for silicate depression), starch (for carbonate depression) pH Modifier: Sodium carbonate (adjusting pH to 9-10) Process Flow: ①Grind ore to 70-80% passing 0.074mm ②Condition pulp sequentially with depressants and collectors ③Float phosphate minerals ④Dewater concentrates to obtain final product Applicable Ore Type: Siliceous phosphate ore (phosphate-quartz association) 2.3.2 Reverse Flotation (Gangue Mineral Flotation) Reagent Scheme: Collector: Amine compounds (e.g., dodecylamine) for silicate flotation Depressant: Phosphoric acid for phosphate mineral depression Applicable Ores: Calcareous phosphate ores (phosphate-dolomite/calcite associations) 2.3.3 Double Reverse Flotation A two-stage process: ①Primary flotation of carbonates; ②Secondary flotation of silicates Applicability: Siliceous-calcareous phosphate ores (e.g., Yunnan/Guizhou deposits in China) Advantages: Capable of processing low-grade ores (P₂O₅

Flotation of Non-ferrous Metal Ores and Mixed Ores

Under surface weathering conditions, primary sulfide minerals undergo oxidation reactions with atmospheric oxygen and aqueous solutions, forming secondary oxidized mineral zones. These oxidation zones typically develop in the shallow portions of ore deposits, with their thickness controlled by regional geological conditions, ranging between 10-50 meters.   Based on the oxidation degree of metallic elements in the ore (i.e., the percentage of oxidized minerals relative to total metal content), ores can be classified into three categories: Oxidized ore: oxidation rate >30% Sulfide ore: oxidation rate 10 (leads to PbS film detachment) Process optimizations: ✓ Partial NaHS substitution for Na₂S ✓ pH adjustment with (NH₄)₂SO₄ (1-2 kg/t) or H₂SO₄ ✓ Staged reagent addition (test-determined)   1.2. Zinc Oxide Minerals and Flotation Methods 1.2.1. Principal Industrial Zinc Oxide Minerals Mineral Chemical Formula Zinc Content Density (g/cm³) Hardness Smithsonite ZnCO₃ 52% 4.3 5 Hemimorphite H₂Zn₂SiO₅ 54% 3.3–3.6 4.5–5.0 1.2.2 Flotation Process Options 1.2.2.1. Hot Sulfidization Flotation Key Parameters: Pulp Temperature: 60–70°C (critical for ZnS film formation) Activator: CuSO₄ (0.2–0.5 kg/t) Collector: Xanthates (e.g., potassium amyl xanthate) Applicability: Effective for smithsonite Limited efficiency for hemimorphite 1.2.2.2. Fatty Amine Flotation Process Control: pH Adjustment: 10.5–11 (using Na₂S) Collector: Primary fatty amines (e.g., dodecylamine acetate) Slime Management: Option A: Pre-flotation desliming Option B: Dispersants (sodium hexametaphosphate + Na₂SiO₃) Innovative Approach: Amine-Na₂S emulsion (1:50 ratio) Eliminates need for desliming   1.3. Beneficiation Processes for Mixed Lead-Zinc Ores 1.3.1. Process Flow Options 1.3.1.1. Sulfides-First, Oxides-Later Circuit Sequence: Sulfide minerals (bulk/selective flotation) → Oxidized lead → Oxidized zinc Advantages: Maximizes sulfide recovery before oxide treatment Reduces reagent interference between mineral types 1.3.1.2. Lead-First, Zinc-Later Circuit Sequence: Lead sulfides → Lead oxides → Zinc sulfides → Zinc oxides Advantages: Ideal for ores with clear Pb/Zn liberation boundaries Enables tailored reagent schemes for each metal 1.3.2. Process Optimization Guidelines Highly oxidized ores (ZnO >30%): Use amine collectors to co-recover: Oxidized zinc minerals Residual zinc sulfides Typical dosage: 150–300 g/t C12–C18 amines Process selection criteria: Requires: Ore characterization studies (MLA/QEMSCAN) Bench-scale testing (including locked-cycle tests) Decision factors: Oxidation ratio (PbO/ZnO vs. PbS/ZnS) Mineralogical complexity index     2. Flotation Characteristics of Multivalent Metal Salt Minerals 2.1. Representative Minerals Phosphates: Apatite [Ca₅(PO₄)₃(F,Cl,OH)] Tungstates: Scheelite (CaWO₄) Fluorides: Fluorite (CaF₂) Sulfates: Barite (BaSO₄) Carbonates: Magnesite (MgCO₃) Siderite (FeCO₃) 2.2. Key Flotation Properties Characteristic Description Crystal Structure Dominant ionic bonding Surface Properties Strong hydrophilicity (contact angle

Flotation of Copper Oxide Mines and Their Mixed Ores

  The common main Copper Oxide minerals include: Malachite (CuCO3-Cu(OH)2, Copper 57.4%, density 4g/cm³, hardness 4); Azurite (2CuCO3 · Cu (OH)2, Copper 55.2%, density 4g/cm³, hardness 4). In addition, there are also Chrysocolla (CuSiO3 · 2H2O, Copper 36.2%r, density 2-2.2g/cm³, hardness 2-4) and Chalcopyrite (Cu2O, Copper 88.8%, density 5.8-6.2g/cm³, hardness 3.5-4).   Fatty acid collectors have good collection performance for non-ferrous metal oxide minerals, but due to poor selectivity (especially when the gangue is a carbonate mineral), it is difficult to improve the concentrate grade. Among the xanthate collectors, only high-grade xanthate has a certain collection effect on non-ferrous metal oxide minerals. However, the method of directly using xanthate flotation to Oxidize Copper ore without sulfurization treatment has not been widely used in industrial applications due to its high cost. In practical applications, the following methods are more common:   ① Sulfurization method -- the most common and simple process, suitable for flotation of all sulfidizable Copper Oxide ores. After sulfurization treatment, the oxidized ore has the characteristics of sulfide ore and can be floated using xanthate. Malachite and Chalcopyrite are easy to sulfide with sodium sulfide, while Siliceous Malachite and Chalcopyrite are more difficult to sulfide. During the sulfurization process, the dosage of sodium sulfide can reach 1-2kg/(t of raw ore). Due to the easy oxidation and short reaction time of sulfurizing reagents such as sodium sulfide, the generated sulfurized film is not stable enough, and strong stirring can easily cause detachment. Therefore, it should be added in batches without prior stirring and directly added to the first tank of the flotation machine. During sulfurization, the lower the pH value of the slurry, the faster the sulfurization rate. When there is a large amount of mineral mud that needs to be dispersed, a dispersant should be added, usually using sodium silicate. Generally, butyl xanthate or mixed with dithiophosphate is used as a collector. The pH value of the slurry is usually maintained at around 9. If it is too low, lime can be added appropriately to adjust it.   ② Organic acid flotation method -- Organic acids and their soaps can effectively float Malachite and Chalcopyrite. If the gangue mineral does not contain carbonates, this method is applicable; Otherwise, flotation will lose its selectivity. When the gangue is rich in floatable iron and manganese minerals, it can also lead to a deterioration of flotation indicators. When using organic acid collectors for flotation, sodium carbonate, sodium silicate, and phosphate are usually added as gangue depressants and slurry adjusters. There are also cases in practice where sulfurization method is combined with organic acid flotation method. Firstly, sodium sulfide and xanthate are used to flotation Copper Sulfide and partial copper oxide, followed by organic acid flotation of the remaining Copper Oxide.   ③ Leaching-precipitation-flotation method--used when both sulfurization and organic acid methods cannot obtain satisfactory results. This method utilizes the easy solubility of Copper Oxide minerals by first leaching the oxide ore with sulfuric acid, then replacing it with iron powder to precipitate Copper metal, and finally floating the precipitated Copper through flotation. Firstly, it is necessary to grind the mineral to a monomer dissociation state (-200 mesh accounting for 40%~80%) according to its embedding particle size. The leaching solution adopts a dilute sulfuric acid solution of 0.5%~3%, and the amount of acid is adjusted between 2.3~45kg/(t of raw ore) according to the properties of the ore. For ores that are difficult to leach, heating (45~70℃) leaching can be used. The flotation process is carried out in an acidic medium, and the collector is chosen to be cresol dithiophosphate or bis xanthate. The undissolved Copper sulfide minerals float up together with the precipitated Copper metal and eventually enter the flotation concentrate.   ④ Ammonia leaching-sulfide precipitation-flotation method -- suitable for situations where ores are rich in a large amount of alkaline gangue, acid leaching consumes a large amount and is costly. This method first grinds the ore finely, and then adds sulfur powder for ammonia leaching treatment. During the leaching process, Copper ions in the oxidized copper ore react with NH3 and CO2, while being precipitated by sulfur ions to form new copper sulfide particles. Next, ammonia is recovered by evaporation and copper sulfide flotation is carried out. The pH value of the slurry needs to be controlled between 6.5 and 7.5, and excellent flotation results can be achieved using conventional copper sulfide flotation reagents. It is worth noting that the recycling of ammonia must be taken seriously to prevent environmental pollution.   ⑤ Segregation-flotation -- its core is to mix ore with suitable particle size, 2%~3% coal powder, and 1%~2% salt, and then perform Chlorination reduction roasting in a high temperature environment of 700-800℃ to generate copper chloride. These chlorides evaporate from the ore and are reduced to metallic Copper in the furnace, which then adsorbs onto the surface of coal particles. Subsequently, Copper metal was effectively separated from gangue through flotation method. This method is particularly suitable for processing difficult to select copper oxide ores, especially complex Copper oxide ores with high mud content and combined Copper accounting for more than 30% of the total Copper content, as well as ores rich in Malachite and Chalcopyrite. In the comprehensive recovery of Gold, Silver, and other rare metals, the separation method exhibits significant advantages compared to the leaching flotation method. However, its disadvantage is that it consumes a large amount of heat energy, resulting in relatively high costs..   ⑥ Flotation of mixed Copper ore -- the flotation process of mixed Copper ore should be determined based on experimental results. The available processes include: firstly, synchronous flotation of oxidized minerals and sulfide minerals after sulfidation; The second is to first flotation sulfide minerals, and then flotation oxidized minerals after sulfidizing tailings. When simultaneously flotation Copper oxide minerals and Copper sulfide minerals, the process conditions are basically the same as those for flotation of oxide minerals, but it should be noted that as the oxide content in the ore decreases, the amount of sodium sulfide and collector should be correspondingly reduced. There are usually two main processes used for the treatment of Copper Oxide ores abroad: sulfide flotation and acid leaching precipitation flotation.  

Precautions for Gold Extraction by Crushing and Heap Leaching of Gold Mines

Today, we will explore several key points that require special attention in the Gold mine crushing process.   In the process of Gold mine fracture pile extraction, the following key matters should be paid attention to: 1. Ore property analysis Mineral composition: master the Gold content in the ore and its associated minerals in the ore to ensure the applicability of heap leaching method. Particle size distribution: the particle size of the crushed ore should be uniform, as too large or too small will affect the leaching effect.   2. The crushing process Crushing equipment: select the appropriate crusher, such as jaw crusher, cone crusher, to ensure that the ore reaches the ideal grain size. Particle size control: generally controlled within the range of 10-30 millimeters. If it is too large, it will reduce the leaching rate, while if it is too small, it will easily produce fine mud and hinder the penetration of the solution.   3. Preparation of the heap leaching site Site selection: select a flat ground with good anti-seepage performance to prevent environmental pollution caused by solution leakage. Anti-seepage treatment: laying high standard anti-seepage membrane to effectively blocks the leaching solution into the ground.   4. Selection and use of leaching reagent Leaching reagent: usually choose Sodium Cyanide solution, need to accurately control its concentration (0.05% -0.1%), too high will increase the cost, too low will affect the leaching efficiency. The Eco-friendly Gold Leaching Reagent YX500 can replace Sodium Cyanide with the same amount or increase the amount to improve leaching efficiency. PH value regulation: keep the PH value in the range of 10-11 to prevent Cyanide decomposition.   5. Heap leaching operation points Heap height control: the heap height is generally set to 3-6 meters, too high will hinder the penetration of solution, and too low will reduce the operation efficiency. Spray strength: the spray strength should be controlled at 5-10 L / m² · h, too large will easily lead to the loss of solution, too small will affect the leaching effect.   6. Management of the leaching solution Leaching solution collection: Ensure that the leaching solution is effectively collected to prevent its loss and contamination. Leaching solution cycle: recycle leaching solution to improve gold recovery and reduce consumption of reagents.   7. Environmental protection Wastewater treatment: the leaching liquid must be strictly treated before discharge to prevent pollution to the environment. The eco-friendly Gold Leaching Reagent YX500 has minimal environmental and ecological pollution, and can meet the requirements of environmental policies. Tailings treatment: the leaching tailings should be properly disposed of to avoid secondary pollution.   8. Safety management Cyanide management: In view of the highly toxic characteristics of Cyanide, strict management measures must be implemented to prevent the occurrence of leakage and poisoning events. The eco-friendly Gold Leaching Reagent YX500 has been tested by a third party and verified as a low toxicity and environmentally friendly product, which is easy to manage. Personnel protection: Operators must wear corresponding protective equipment and receive regular safety training to ensure safe operation.   9. Equipment maintenance Regular inspection: regular comprehensive inspection of crushing, spraying and other equipment to ensure its stable operation. Timely maintenance: once the equipment fault is found, repair immediately to prevent affecting the production schedule.   10. Cost control Reagent cost: reasonable optimization of reagent use plan, effectively reduce the cost expenditure. Energy consumption control: optimize the crushing and spray process process to significantly reduce energy consumption. The above mentioned items are common precautions in the process of Gold mine crushing pile extraction, and multiple factors such as ore characteristics, process parameters, environmental protection and safety management should be comprehensively considered to improve the Gold recovery rate.

What Are The Commonly Used Mineral Processing Methods?

Heavy-Media Process   1. Method   The heavy medium beneficiation method utilizes the density differences (or particle size differences) of different ore particles in the ore, and creates an ideal loose layering and separation environment through the principles of fluid dynamics and various mechanical forces, in order to achieve effective separation of different materials. 2. Principle   According to Archimedes' principle, particles with a density lower than that of a heavy medium will float up, while particles with a density higher than that of a heavy medium will sink. 3. Process flow   The ore reselection process consists of a series of continuous operational steps. The nature of these operational steps can be divided into three main parts: preparation operation, selection operation, and product processing operation.   (1) The preparation process includes the following aspects:    a) The crushing and grinding operations carried out to dissociate useful mineral monomers;    b) For ores with high levels of pectin or clay, perform ore washing and desliming operations;    c) Particle size classification of selected ores is carried out through screening or hydraulic grading methods. After ore classification, they are selected separately, which is beneficial for selecting better operating conditions and improving sorting efficiency.   (2) The sorting operation is the core process of ore sorting. The complexity of the sorting process varies, and simple processes may only consist of a single unit operation, such as heavy medium sorting.   (3) The product processing operation mainly involves processes such as concentrate dewatering, tailings transportation, and storage.     Jigging   1. Principle   Jigging is a beneficiation method that utilizes the effect of vertical alternating medium flow to loosen the mineral particle group and stratify it according to density differences. During this process, lighter minerals will float to the upper layer, known as light products; And heavier minerals sink to the lower layer, called heavy products, to achieve mineral separation. If the density of the medium increases within a certain range, the density difference between mineral particles will also increase accordingly, thereby improving the sorting efficiency. The equipment that completes the jigs process is called a jigs. After being fed into the jig, the ore dressing material will fall onto the sieve plate to form a dense layer of material, which is called the bed layer. At the same time as the material is fed in, the lower part of the jigs is periodically supplied with alternating water flow. This vertical variable speed water flow enters the bed through the sieve holes, and the minerals undergo the jigs sorting process in this water flow. 2. Technological process   When the water flow rises, the bed is lifted up, presenting a loose and suspended state. At this point, the mineral particles in the bed begin to move relative to each other and undergo stratification based on their inherent characteristics such as density, particle size, and shape. Even before the water flow stops rising and turns downward, due to inertia, the mineral particles are still moving, and the bed continues to loosen and stratify. When the water flow turns downward, the bed gradually becomes tighter, but stratification is still ongoing. When all the mineral particles fall back onto the sieve surface, the possibility of relative motion between them is lost, and the stratification process basically stops. At this point, only those mineral particles with higher density and finer particle size pass through the gaps between the large blocks of material in the bed and continue to move downwards. This phenomenon can be seen as a continuation of the stratification phenomenon. When the descending water flow ends, the bed is completely tight and the stratification temporarily stops. The time required for the water flow to complete a periodic change is called the jig cycle. During a jig cycle, the bed undergoes a process of layering from tight to loose and then to tight again, and the particles are subjected to sorting. Only after multiple cycles of beating can the stratification gradually improve. Ultimately, high-density mineral particles concentrate in the lower part of the bed, while low-density mineral particles gather in the upper layer. Subsequently, two products with different densities and masses were obtained by discharging them separately from the jigs.     Flotation   1. Principle   Flotation is a mineral processing technique that utilizes the differences in physical and chemical properties of mineral surfaces for sorting. 2. Flotation process   The flotation process includes grinding, grading, slurry adjustment, as well as the coarse selection, fine selection, and sweeping stages of flotation. In these processes, the grinding flotation process can be subdivided into single-stage grinding flotation process, multi-stage process of segmented grinding flotation, and process of re grinding and re selection of concentrate or intermediate ore. In flotation operations, the step of producing coarse concentrate is called roughing; The process of re selecting coarse concentrate is called selection; The step of recycling tailings again is called scanning selection. When the goal is to recover multiple useful minerals from the ore, priority flotation or selective flotation processes can be selected based on mineral characteristics, that is, all useful minerals are first floated out before separation; Alternatively, a mixed separation flotation process can be adopted, where all useful minerals are first floated out before separation. In industrial production practice, it is necessary to select appropriate reagent formulas and flotation processes based on the characteristics of the ore and product requirements. The basic process of flotation, which is the core structure of the process flow, usually involves key elements such as the number of stages, the number of cycles, and the flotation sequence of minerals. 3. Flotation machine:   The types of flotation machines include mechanical agitation flotation machines, inflatable flotation machines, mixed flotation machines or inflatable agitation flotation machines, and gas precipitation flotation machines.   (1) The mechanical stirring flotation machine has the following characteristics: the aeration and stirring of the slurry are both achieved through a mechanical stirrer, and it is an external air self-priming flotation machine. Its inflatable mixer has the suction function of a pump, which can simultaneously suck up air and slurry.   (2) The significant features of the inflatable agitation flotation machine are: the aeration amount can be independently adjusted, the wear degree of the mechanical agitator is relatively small, the beneficiation index is superior, and the energy consumption is low.   (3) The characteristic of the Denver type flotation machine is that it has a large effective aeration capacity and can form an upward flow of slurry in the tank.   (4) The structural features of an inflatable flotation machine include the absence of mechanical agitators and transmission components. The inflation method is to inflate through an inflator, and the size of the bubbles can be controlled by adjusting the structure of the inflator. The mixing method of bubbles and slurry is countercurrent mixing. Its main application is to process rough and sweeping operations with simple composition, high grade, and easy beneficiation.   (5) Gas precipitation flotation machine is mainly used for the flotation of fine-grained minerals and the de oiling flotation of oily wastewater.     Magnetic Separation   1. Principle   Magnetic separation is a process that utilizes the magnetic differences between different ores or materials to separate them under the influence of magnetic and other related forces. 2. Magnetic Separation Process   The magnetic separation process is a magnetite beneficiation technology that combines dry and wet methods. This process mainly involves three-stage magnetic separation of mineral powder, followed by wet material magnetic separation. In the magnetic separation process, the magnetic field strength range used is 400 to 1200 Gauss (GS), and the speed of the magnetic drum is set between 60 to 320 revolutions per minute. After dehydration treatment, the wet material is converted into finished iron concentrate powder. For ores with a general iron content of 35%, after this magnetic separation process, the iron content of the iron concentrate powder can be increased to 68% to 70%. This joint process method has achieved a utilization rate of up to 90% for ore. During the manufacturing process, the water consumption is significantly reduced, thereby saving water resources, lowering production costs, and reducing environmental pollution. In addition, the dust generated during the magnetic separation process is effectively captured by specialized dust removal devices, avoiding air pollution. Overall, this method is an innovative process with high production efficiency, excellent product quality, and environmental friendliness.   Chemical beneficiation   1. Principle   Chemical beneficiation is a resource processing technology that uses chemical methods to change the composition of material components based on their chemical properties, and uses other methods to enrich the target components. This process mainly includes two key steps: chemical leaching and chemical separation. 2. Process:   (1) Usually, ores processed by chemical beneficiation are mostly lean, fine-grained, and complex ores. Based on the occurrence state of the target mineral, the roasting process is indispensable as it prepares for the subsequent leaching steps and facilitates the precipitation of the target mineral. Due to the existence of certain elements in minerals in the form of isomorphism, their precipitation process requires the destruction of the mineral lattice structure. According to the different additives, temperature, and pressure used, calcination can be divided into various types, such as chlorination calcination, calcification calcination, and high-temperature calcination.   (2) The purpose of the leaching step is to transfer useful elements in ionic form into the leaching solution, preparing for the subsequent solid-liquid separation steps. According to different leaching conditions, there are also various classifications of leaching processes, similar to roasting.   (3) Solid liquid separation refers to the process of separating the leached residue from the leachate.

How to prevent accidents caused by mining machinery injuries

The main causes of accidents causing mechanical injuries are: 1. Neglecting safety measures during maintenance, inspection of machinery, and handling of hidden dangers: Serious consequences have been caused by maintenance personnel entering equipment (ball mills, crushers, etc.) for maintenance, inspection operations, or handling of safety hazards without cutting off the power supply, hanging warning signs that prohibit closing, or setting up dedicated personnel for supervision. Accidents were also caused by misjudgment due to factors such as timed power switches or temporary power outages at that time. There are also cases where, although the equipment is powered off, work is carried out before the inertial operation of the equipment is completely stopped, resulting in serious consequences; 2. Lack of safety devices. If some mechanical transmission belts, gear machines, couplings close to the ground, pulleys, flywheels and other equipment parts that are prone to harm the human body do not have intact protective devices; Some equipment parts such as entry holes, feeding ports, and cage wells lack guardrails and cover plates, and there are no warning signs. If operators accidentally touch these parts, accidents can occur; 3. The layout of the power switch is unreasonable. One situation is not to stop immediately in case of an emergency; Another situation is that several mechanical switches are set together without distinguishing them, which can easily cause serious consequences due to accidental opening of the machinery; 4. Self made or arbitrarily modified mechanical equipment that does not meet safety requirements; 5. In running machinery, perform tasks such as cleaning, jamming, and applying belt wax (such as cleaning waste on running belts); 6. Unauthorized entry into hazardous work areas for mechanical operation (such as sampling, working, passing, picking, etc.); 7. Personnel without the ability to operate machinery or other unauthorized personnel tampering with machinery.   Preventive measures to prevent mechanical injury accidents: 1. The maintenance of machinery must strictly follow the system of power-off, hanging warning signs prohibiting closing, and assigning dedicated personnel for supervision. After the mechanical power is cut off, it must be confirmed that its inertia operation has been completely eliminated before starting work. After the mechanical maintenance is completed and before the trial operation, a detailed inspection of the site must be carried out to confirm that all personnel in the mechanical parts have been completely evacuated before the gate can be closed. During maintenance and testing, it is strictly prohibited for anyone to stay inside the equipment for vehicle counting; 2. Machinery that operators frequently touch with their hands must have a sound emergency brake device, and the position of the brake button must be such that the operator can reach it at any time within the range of mechanical operation; Each transmission part of mechanical equipment must have reliable protective devices; Each inlet, feeding port, screw conveyor and other equipment parts must have cover plates, guardrails and warning signs; Maintain a clean and hygienic working environment; 3. The layout of each mechanical switch must be reasonable and comply with two standards: first, it must be convenient for the operator to stop urgently; Secondly, to avoid accidentally activating other devices; When cleaning up accumulated materials, poking stuck materials, and applying belt wax to machinery, the system of hanging warning signs when shutting down and cutting off power should be followed; 4. It is strictly prohibited for unrelated personnel to enter the mechanical operation site with high risk factors. If non mechanical operators must enter due to personal reasons, they must first contact the on duty mechanical operator and have safety measures in place before agreeing to enter; 5. Personnel operating various types of machinery must undergo professional training, be able to master the basic knowledge of the equipment's performance, pass the examination, and hold a certificate to work. During on-the-job work, it is necessary to operate carefully, strictly follow relevant rules and regulations, use labor protection equipment correctly, and strictly prohibit unlicensed personnel from operating mechanical equipment.   In order to further enhance the safety of mechanical operations, the following additional measures should be taken: 1. Regularly inspect and maintain mechanical equipment to ensure that all safety devices and protective facilities are in good condition, and promptly replace or repair damaged components; 2. Provide regular safety education and training to operators, strengthen safety awareness, and ensure that they understand and comply with operating procedures; 3. Set up clear safety warning signs in the mechanical operation area, such as danger zone warnings, operating procedures instructions, etc., to remind operators to pay attention to safety; For complex mechanical operations, detailed operation manuals and emergency plans should be developed to respond quickly and effectively in emergency situations; 5. Establish and improve accident reporting and investigation mechanisms, thoroughly investigate every accident that occurs, analyze the causes, summarize lessons learned, and prevent similar accidents from happening again; 6. Encourage employees to propose safety improvement suggestions and reward the adopted suggestions to stimulate their enthusiasm for participating in safety management; 7. Install monitoring equipment in the mechanical operation area to monitor the work situation in real time, promptly detect and correct unsafe behaviors. By implementing these comprehensive measures, the incidence of mechanical injury accidents can be greatly reduced, ensuring the safety and physical health of employees.

How to add mineral beneficiation reagents?

The purpose of reasonable addition of reagents is to ensure that the reagents can effectively interact with minerals, thereby achieving selective collection of minerals. In addition, maintaining the maximum efficiency and optimal concentration of reagents in the slurry is also crucial for the stability of mineral processing indicators. Therefore, it is necessary to select the appropriate dosing location and method based on the characteristics of the ore, the properties of the chemicals, and the process requirements.   In practical operation, the selection of dosing points is closely related to the usage of the reagent and also to the dosing points of the reagent that will be replaced. Usually, adjusters (such as lime) are added to the grinding machine to eliminate the activation or repression of "inevitable" ions that may have harmful effects on flotation. Depressants should be added before the collector and can generally be added to the mill or mixing tank. Activating reagents are usually added to the mixing and stirring tank. As for the collector and frother, they are usually added to the buffer tank in front of the mixing tank or flotation machine. For some slowly acting collectors (such as cresol diphenyl dithiophosphate, Dithiophosphate 25, kerosene, etc.), in order to promote their dispersion in the slurry and effective interaction with minerals, and prolong their interaction time with minerals, they are sometimes added to the grinding machine.   The common order of adding reagents during flotation of raw ore is: adjusting reagent - depressant - collector - frother; When flotation of minerals is depressed, the dosing sequence is: activator - collector - frother.   In addition, the selection of dosing points also needs to consider the properties of the ore and other specific conditions. For example, in some copper sulfide flotation plants, adding xanthate to the grinding machine has improved the copper separation index. In addition, when installing a single cell flotation machine in the grinding cycle to recover dissociated coarse ore particles, in order to increase the action time of the collector, it is also necessary to add chemicals to the grinding machine.   In terms of dosing methods, flotation reagents can be added in two ways: one-time addition and batch addition.   One time addition refers to adding a certain reagent to the slurry at once before flotation, so that the concentration of the reagent at a certain operating point is higher and it is more convenient to add. In general, one-time dosing is often used for reagents (such as soda, lime, etc.) that are easy to dissolve in water, are not easy to be taken away by foam machinery, and are not easy to react in the slurry and fail.   Batch dosing refers to adding a certain reagent in several batches during the flotation process. In general, 60% to 70% of the total amount is added before flotation, and the remaining 30% to 40% is added in several batches to appropriate positions. This batch dosing method can maintain the concentration of reagents throughout the flotation operation line, thereby stabilizing the beneficiation indicators.   For the following situations, batch addition should be adopted: (1) For those agents that are difficult to dissolve in water and easy to be taken away by foam (such as oleic acid, aliphatic amine collectors). (2) Reagents that are prone to react or decompose and become ineffective in mineral slurry. For example, carbon dioxide, sulfur dioxide, etc., if only added at one point, will quickly react and fail. (3) For reagents that require strict dosage control. For example, if the local concentration of sodium sulfide is too high, it will lose its selectivity. The duration of action of reagents varies, and commonly used reagents in practice can be determined based on experience. For example, pine oil requires 1-3 minutes of action time, while xanthate requires 1-4 minutes.

How to select iron from iron ore or magnetite

Iron is widely distributed in nature and is one of the earliest discovered and most commonly used metals. There are various types of iron ore with different grades. Iron can be selected through processes such as crushing, grinding, magnetic separation, flotation, and reselection. The main materials with high industrial value are magnetite, hematite, magnetite, ilmenite, limonite, and siderite. 1. Magnetite ore Magnetite is a type of iron oxide ore, which is a common iron ore mineral. It appears black gray with metallic luster and black streaks. Magnetite is widely distributed in the Earth's crust and often coexists with other minerals. The iron content is 72.4% and it has magnetism. Magnetic separation method can be used in mineral processing, which is very convenient. Due to its fine structure, its reduction performance is poor. After long-term weathering, it becomes hematite. 2. Hematite Hematite is also an iron oxide, with a surface color ranging from red to light gray, sometimes black, and dark red streaks. Commonly found in geological environments such as volcanic rocks and sedimentary rocks. Due to their different structural conditions, they can be divided into many categories, such as Red hematite, Specular hematite, Micaceous hematite, and Red Ocher. Pure hematite has an iron content of 70%, with less harmful impurities such as sulfur and phosphorus, and better reducibility than magnetite. 3. Limonite This is an ore containing iron hydroxide, which is a general term for two different structured ores, goethite and phosphorite, and appears as earthy yellow or brown. Commonly found in geological layers such as mudstone and sandstone containing iron. Due to the weathering of other iron ores, brown iron ore has a relatively soft structure, low specific gravity, and high water content. 4. Titanium iron ore Titanium iron ore is an oxide mineral of iron and titanium, appearing gray to black with a slight metallic luster, also known as titanium magnetite. The main application is to extract rare metal titanium. 5. Siderite Siderite is an ore containing ferrous carbonate, mostly in a bluish gray color. This type of ore mostly contains a considerable amount of calcium and magnesium salts. Although its iron content is not high, it is easy to mine and process.     The common beneficiation methods for iron ore mainly include the following, and the beneficiation methods may vary for different types and characteristics of iron ore: Ⅰ. Magnetic ore beneficiation method 1. Single weak magnetic separation process Suitable for easily selected single magnetite ores with simple mineral composition. It can be further divided into continuous grinding weak magnetic separation process and stage grinding stage separation process. Continuous grinding weak magnetic separation process: suitable for ores with coarse particle size or high iron grade. According to the particle size of the iron ore, one stage grinding or two stages of continuous grinding can be used. After the grinding products meet the separation requirements, weak magnetic separation can be carried out. Stage grinding stage separation process: suitable for low-grade ores with finer embedded particle size. After a stage of grinding, magnetic separation coarse selection is carried out, and some qualified tailings are discarded. The magnetic separation coarse concentrate then enters the second stage of grinding for further grinding and selection. 2. Weak magnetic separation reverse flotation process Mainly aimed at the problem of difficulty in improving the grade of iron ore concentrate and the high composition of impurities such as SiO2 in iron concentrate. The process methods include two types: magnetic separation cation reverse flotation process and magnetic separation anion reverse flotation process. 3. Weak magnetic strong magnetic flotation combined process Mainly used for processing polymetallic coexisting iron ores and mixed iron ores. It is divided into weak magnetic separation flotation process, weak magnetic strong magnetic process, and weak magnetic strong magnetic flotation process. Weak magnetic separation flotation process: mainly used for processing magnetite ore with associated sulfides. Weak magnetic strong magnetic process: mainly used for processing mixed ores with low magnetic properties. Firstly, weak magnetic separation is used to separate weak magnetic magnetite, and then strong magnetic separation is used to recover weak magnetic minerals such as hematite from weak magnetic tailings. Weak magnetic strong magnetic flotation process: used for processing more complex polymetallic coexisting iron ores.   Ⅱ. Mineral processing method for hematite ore 1. Roasting and magnetic separation process When the mineral composition is relatively complex and other beneficiation methods are difficult to obtain good separation indicators, magnetization roasting method is often used. For fine ore, methods such as strong magnetic separation, gravity separation, flotation, and their combined processes are commonly used for separation. 2. Flotation process of hematite The flotation process methods include anionic collector forward flotation, cationic collector reverse flotation, and anionic collector reverse flotation, all of which have been applied in industry. The reverse flotation process has advantages over the forward flotation process because the target of the reverse flotation process is gangue, while the target of the forward flotation process is iron minerals. The effective gravity of gangue in flotation pulp is far lower than that of iron minerals, so it is easier to separate gangue minerals in flotation foam by reverse flotation. Therefore, it is easier to separate gangue minerals in flotation foam by reverse flotation. 3. Weak magnetic strong magnetic process The traditional process flow for processing magnet hematite mixed ore. After the weak magnetic separation tailings are concentrated, they are subjected to strong magnetic coarse selection and scanning selection. The strong magnetic coarse concentrate is concentrated and then selected by a strong magnetic separator. 4. Strong magnetic flotation process Due to the small amount of magnetite and other strong magnetic minerals in the ore, it is easy to cause blockage of the strong magnetic field separator, so when using the strong magnetic separation process. It is usually necessary to add a weak magnetic separation operation before the strong magnetic separation operation to remove or separate the strong magnetic minerals in the ore.   Ⅲ.Mineral processing method for brown iron ore 1. Single selection process For ores with high iron grade and good selectivity. Usually, a simple single separation process is used, including reselection, high-intensity magnetic separation, and flotation. Single re-election process: As the main sorting method for brown iron ore, re-election is mainly used to process coarse-grained disseminated ore. Single magnetic separation process: Strong magnetic separation is also a commonly used method for separating limonite, with a simple process and convenient management. Has strong adaptability to ores, and concentrates are easy to concentrate and filter. But for fine-grained mineral mud, the separation effect is poor. Single flotation process: flotation is divided into two process flows: forward flotation and reverse flotation. 2. Joint selection process Including magnetization roasting magnetic separation process, flotation strong magnetic process, reselection strong magnetic process, etc.   Ⅳ.Mineral processing method for siderite ore 1. Roasting magnetic separation technology Magnetic roasting principle: refers to the physical and chemical reactions that occur in a corresponding atmosphere after heating materials or ores to a certain temperature, thereby thermally decomposing weakly magnetic siderite into strongly magnetic magnetite and magnetite. Magnetic roasting classification: Stacked state magnetic roasting, fluidized state magnetic roasting (cooling method will affect the effect of magnetic roasting of siderite). 2. Strong magnetic separation process: Siderite or magnesiosiderite has weak magnetism. Although the ore grade is low and the mineral composition is complex, strong magnetic separation technology can successfully separate weak magnetic iron minerals such as hematite and limonite, including siderite. 3. Flotation process: There are two main flotation processes: positive flotation for iron enrichment and reverse flotation for desilication. The above is an introduction to commonly used methods for iron ore, and the specific situation should be determined based on the actual characteristics of the ore.     Recommend several reagents for iron ore flotation:   Titanium iron collector 【Characteristics】Black paste like solid 【Water soluble】Partially soluble in water 【Specification】750kg/pallet or 25kg/bag 【Typical applicable minerals】Ilmenite 【Function】This product is mainly used for flotation of ilmenite, with good selectivity and can significantly improve the grade of concentrate.   Red magnetite depressant 【Characteristics】White to light yellow powder 【Specification】25kg/bag, 50kg/bag, 1000kg/bag 【Function】Red magnetite depressant, when added to the slurry, can effectively improve the surface hydrophilicity of minerals such as hematite, magnetite, and limonite, effectively inhibiting them and achieving the improvement and reduction of impurities in iron concentrate. Mainly used for reverse flotation of iron ore.   Reverse flotation (silicate) collector 【Characteristics】Light yellow to yellow liquid 【Water soluble】Insoluble 【Specification】900kg/IBC drum 【Function】Efficient ether amine, suitable for removing silicates from hematite and magnetite, easy to biodegrade.
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